INFORMATION CHANGE THE WORLD

International Journal of Engineering and Manufacturing(IJEM)

ISSN: 2305-3631 (Print), ISSN: 2306-5982 (Online)

Published By: MECS Press

IJEM Vol.4, No.1, May. 2014

Synthesis and Characterization of Ni Doped ZnO Nanoparticles

Full Text (PDF, 324KB), PP.10-17


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Author(s)

M.R.A. Bhuiyan, M.K. Rahman

Index Terms

Ni doped ZnO;Compositional uniformity;Structural parameter;Optical parameter

Abstract

This paper discerns key ideas and themes of the possibility of growing Ni doped ZnO nanoparticles by electrochemical method. The purpose is to study the growth mechanism and to optimize the parameters of this method. Upon successful synthesizing the samples, they were characterized using various techniques. XRD, SEM, FTIR, photoluminescence spectroscopy together with the measured optical parameters obtained from UV-VIS absorption testing were analyzed. The X-ray diffraction (XRD) was measured by using a Bruker D8 Advance X-ray diffractometer with CuKα radiation. The surface morphology was investigated using an ‘EVO LS 15’ scanning electron microscope. The FTIR absorption spectra were recorded on a Perkin-Elmer GX FTIR system. The PL spectra were collected on a Jobin Yvon-Horiba Triax 190 spectrometer with a spectral resolution of 0.3 nm. UV-VIS absorption spectrum was recorded by using a UV-VIS spectrophotometer in the photon wavelength range between 300 and 600 nm. XRD pattern reveals that the polycrystalline of hexagonal wurtzite structure and the average size of the particles were estimated to be approximately 61 nm, which conform the nanoparticle. The FTIR result shows the stretching vibration of the Zn-O bond in Ni doped ZnO nanoparticles. There is a green emission peak centered at about 384 nm in the PL behavior. The band edge is shifted to the lower energy side of the Ni doped ZnO nanoparticle. Analyzing the results of various types of characterizations, it has been assessed that Ni doped ZnO nanoparticles was successfully synthesized.

Cite This Paper

M.R.A. Bhuiyan, M.K. Rahman,"Synthesis and Characterization of Ni Doped ZnO Nanoparticles", IJEM, vol.4, no.1, pp.10-17, 2014.DOI: 10.5815/ijem.2014.01.02

Reference

[1]Xia B, Lenggoro W, Okuyama K. Novel route to nanoparticle synthesis by salt-assisted aerosol decomposition. Adv Mater 2001; 13: 1579-82.

[2]Lakshmi BB, Dorhout KP, Martin RC. Sol-gel template synthesis of semiconductor nanostructures. Chem Mater 1997; 9:857-62.

[3]Kobayashi S, Hanabusa K, Suzuki M, Kimura M, Shirai H. Preparation of TiO2 fiber in a sol-gel system containing organogelator. Chem Lett 1999; 10:1077-78.

[4]Kobayashi S, Hanabusa K, Hamasaki N, Kimura M, Shirai H, Shinkai S. Preparation of TiO2 hollow-fibers using supramolecular assemblies. Chem Mater 2000; 12: 1523-25.

[5]Rao RNC, Satishkumar CB, Govindaraj A. Ziconia nanotubes.Chem Commun 1997; 16:1581-82.

[6]Satishkumar CB, Govindaraj A, Nath M, Rao NC. Synthesis of metal oxide nanorods using carbonnanotubes as templates.J Mater Chem 200; 10:2115-19.

[7]Li T, Qiu H, Wu P, Wang M, Ma R. Characteristics of Ni-doped ZnO:Al films grown on glass by direct current magnetron co-sputtering. Thin Solid Films 2007; 515:3905-09.

[8]Ueda K, Tabata H, Kawai T. Magnetic and electric properties of transition-metal-doped ZnO films. Appl Phys Lett 2001; 79:988-90.

[9]Wakano T, Fujimura N, Morinaga Y, Abe N, Ashida A, Ito T. Magnetic and magneto-transport properties of ZnO:Ni films. Physica E 2001; 10:260-64.

[10]Liu E, Xiao P, Chen JS, Lim BC, Li L. Ni doped ZnO thin films for diluted magnetic semiconductor materials. Current Appl Phys 2008; 8:408-11.

[11]Pandey B, Ghosh S, Srivastava P, Avasthi DK, Kabiraj D, Pivin JC. Synthesis and characterization of Ni doped ZnO: A transparent magnetic semiconductor. J Mag Mag Mat 2008; 320:3347-51.

[12]Thota S, Kukreja LM, Kumar J. Ferromagnetic ordering in pulsed laser deposited Zn1 ? xNixO/ZnO bilayer thin films. Thin Solid Films 2008; 517:750-54.

[13]Reetz MT, Helbig W. Size-selective synthesis of nanostructured transition metal clusters. J Am Chem Soc1994; 116:7401-02.

[14]Oh BY, Jeong MC, Kim DS, Lee W, Myoung JM. Post-annealing of Al-doped ZnO films in hydrogen atmosphere. J Cryst Growth 2005; 281:475-80. 

[15]Mahmoud WE, Al-Ghamdi AA, El-Tantawy F, Al-Heniti S. Synthesis, characterization and charge transport mechanism of CdZnO nanorods. J Alloys Compd 2009; 485:59-63.

[16]Al-Harbi T. Hydrothermal synthesis and optical properties of Ni doped ZnO hexagonal nanodiscs. J Alloys Compd 2011; 509:387-90.

[17]Cong CJ, Hong JH, Liu QY, Liao L, Zhang KL. Synthesis, structure and ferromagnetic properties of Ni-doped ZnO nanoparticles. Solid State Communications 2005; 138:511-15.

[18]Radovanovic PV, Gamelin DR. High-temperature ferromagnetism in Ni 2+ doped ZnO aggregates prepared from colloidal diluted magnetic semiconductor quantum dots. Phys Rev Lett 2003; 91:157202-205. 

[19]Wang Y, Liao X, Huang Z, Yin G, Gu J, Yao Y. Preparation and characterization of Ni-doped ZnO particles via a bioassisted process. Coll and Surf A: Physchem Engg Aspects 2010; 372:165-71.

[20]Kong YC, Yu DP, Zhang B, Fang W, Feng SQ. Ultraviolet-emitting ZnO nanowires synthesized by a physical vapor deposition approach. Appl Phys Lett 2001; 78:407-09.

[21]Yang JH, Wang DD, Yang LL, Zhang YJ, Xing GZ, Lang JH, Fan HG, Gao M, Wang Y. Effects of supply time of Ar gas current on structural properties of Au-catalyzed ZnO nanowires on silicon (1 0 0) grown by vapor–liquid–solid process. J Alloys Compd 2008; 450:508-11.

[22]Vanheusden K, Seager CH, Warren WL, Tallant DR, Voigt JA. Correlation between photoluminescence and oxygen vacancies in ZnO phosphors. Appl Phys Lett 1996; 68:403-05.

[23]Vanheusden K, Warren WL, Seager CH, Tallant DR, Voigt JA, Gnade BE. Mechanisms behind green photoluminescence in ZnO phosphor powders. J Appl Phys 1996; 79:7983-90.

[24]Schwartz DA, Kittilatved KR, Gamelin DR. Above-room-temperature ferromagnetic Ni 2+ doped ZnO thin films prepared from colloidal diluted magnetic semiconductor quantum dots. Appl Phys Lett 2004; 85:1395-97.